Asymmetric transfer hydrogenation of 3-nitroquinolines: facile access to cyclic nitro compounds with two contiguous stereocenters.
نویسندگان
چکیده
Hi, neighbor! The first organocatalyzed asymmetric transfer hydrogenation of aromatic nitro compounds was successfully developed with up to 99 % ee. The new methodology provides a direct and facile access to enantiopure cyclic nitro compounds with two contiguous stereocenters.
منابع مشابه
Palladium-catalyzed asymmetric hydrogenation of 3-phthalimido substituted quinolines.
Homogeneous Pd-catalyzed asymmetric hydrogenation of 3-phthalimido substituted quinolines was successfully developed, providing facile access to chiral substituted tetrahydroquinolines bearing two contiguous stereogenic centers with up to 90% ee.
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ورودعنوان ژورنال:
- Chemistry, an Asian journal
دوره 8 7 شماره
صفحات -
تاریخ انتشار 2013